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Arctic Leaf

Star light, star bright: Wishing for a cleaner, less-expensive fuel

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Star light, star bright, I wish I may, I wish I might, have this wish I wish tonight… How many of you said these words on a starry night, particularly if you were with your best girl or boyfriend as a teenager? Or, as a loving parent, how many of you taught your child to say these words as part of your effort to build his or her vocabulary or memory…or just to instill their capacity to dream?

Now Kate Gordon, the, legitimately well respected, president of Next Generation, seems to have forgotten the difference between wishing, hoping, dreaming and reality. Her recent brief “expert” article in the Wall Street Journal departs from reasonable projection into fanciful wishes.

Gordon is correct that the “average car” on the U.S. road is about 11 years old and that their negative impact on GHG emissions and our health is significant. She is also correct in pointing to the large impact that high gas prices have on “our wallets,” (I would add) particularly for low and moderate-income households. Clearly, for the poor and near-poor families and for the economically fragile moderate-income households, present gas prices mean less of the basic necessities: modest job choices, good food, housing and healthcare.

Where Gordon and I part company is with her suggestion that an auto replacement initiative or what she calls an Enhanced Fleet Modernization programs would generate a visible, short-term impact and would likely be supported now, by assumedly the federal or state governments, in a significant way. (I should indicate that while I was head of the urban policy in the Carter administration, HUD senior officials thought about offering support by providing older cars to carless, low-income folks to permit them to secure job opportunities in the suburbs. How times have changed. The concern about GHG emissions and other pollutants emitted from older cars that run on gasoline are now seen as a real environmental problem.) The difficulty with Ms. Gordon’s proposal is number one, money and bureaucracy; number two, money and bureaucracy; and number three, money and bureaucracy. Even California, which she touts, has had mixed results with its replacement and incentives to replace older car programs. Clearly, exporting California’s experience to many other states, given economic and political constraints, would be difficult and would likely result annually in a relatively small impact on the nearly 300,000,000 cars in the U.S of which approximately 85-90 percent are over six years old.

Car replacement is a nice thought, but probably, at this time, an exotic one. If policymakers are seriously looking for a way for large numbers of owners of older cars to immediately reduce their vehicle’s negative effect on the environment, air quality and their own costs of fuel, there are better ways. While we wait and hope for the advent of vehicles that are ready to run on renewable fuels and that simultaneously meet the travel as well as budget needs and demands of most low, moderate and middle-income Americans, we should look at natural-gas-based ethanol as a fuel for newer flex fuel cars and for large numbers of older vehicles converted to flex-fuel vehicles.

Ethanol is not perfect as a fuel but it is better than gasoline. It emits fewer GHG emissions and other pollutants harmful to the nation’s quality of life. Recent regulations, like ones initiated by Colorado, that significantly reduce emissions from drilling now will likely make life cycle environmental evaluations of natural gas changed into ethanol a much better environmental deal. The process appears technologically feasible at a cost lower than the production costs of gasoline. If ethanol is allowed to compete with gasoline by oil companies on an even playing field — oil companies generally control who gets what and where at most “gas” stations — ethanol will be cheaper than gasoline for the consumer.

It is relatively inexpensive to convert older cars to flex-fuel vehicles — perhaps as little as $100 to $200. Finding a way through lessening the cost of certification to expand the number of conversion kits certified by the EPA and, or, where relevant, allowing recalibration of software and engines, would expand the benefit-cost ratio for many older cars. Star light, star bright, we can have the wish we wish tonight concerning a cleaner environment and lower consumer prices in a relatively short time, while we continue to push for electric vehicles and a whole range of renewable fuels to achieve prime-time performance for most Americans.

Arctic Leaf

Take me shopping for eggs, copper and corn starch

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Good news for a world often filled with bad news has recently been generated by two major U.S. universities, both in regards to the efficacy of alternative fuels. Maybe the announcements will lend confidence that America can find a way to balance economic growth with environmental concerns. Increasing success over time will mean that (paraphrasing in part, the late Sen. Robert Kennedy) the nation will not have to accept “what is” with respect to the dominance of gasoline as a fuel, but can consider “what could be” concerning the use of alternative, cleaner, safer, environmental-better and cheaper fuels.

Stanford University professors, in a paper co-authored by Dr. Matthew Kanan, assistant professor of chemistry, announced that they have developed a copper catalyst that can efficiently convert carbon monoxide and water into ethanol. Quoting from a recent MIT Technology Review (April 2014), “while the work is still experimental, it’s significant because the group was able to synthesize ethanol and other desired products with so little energy input.” The Stanford researchers envision a “two-step process in which carbon dioxide is first converted into carbon monoxide using either existing processes or more energy-efficient ones that are currently under development. Then, the carbon monoxide would be converted to ethanol or other carbon-based compounds electrochemically. The key to the new catalyst is preparing the copper in a novel way that changes its molecular structure.”

How long will it take to get from idea to market? If the copper-based process survives further lab tests and evaluations, and if it is then converted into a prototype that is able to produce ethanol fuel, a big push to convert the prototype to real-world status from both the private sector and government would be warranted.

Stanford’s “breakthrough” — if the process becomes marketable and can generate lower-priced, environmentally-safe ethanol that is capable of fueling flex-fuel vehicles (FFVs) and older, converted FFVs — will be significant, even perhaps a disruptive technology. With the proper support, hopefully in the not-too-distant future, increased use of the copper catalyst will minimize and maybe even end the food vs. fuel and land-use allocation fights, as well as help resolve GHG emissions and other pollutant issues that have sometimes frustrated the use of corn-based ethanol and muted receptivity to natural-gas-based ethanol. Technological improvements concerning production reflected in recent life-cycle analysis of corn-based ethanol and reasonable assumptions concerning the cost and environmental benefits of natural-gas-based ethanol, combined with the success of Stanford’s copper catalyst approach, could offer owners of FFVs (both converted and new vehicles) a wider variety of alternatives to secure ethanol that, clearly, will be cheaper, safer and better for the environment.

Stanford’s good news was matched by Cornell’s. Dr. Yingchao You and Dr. Hao Chen announced that they had discovered that a component of corn starch and the yolk shell structure of eggs improve the durability and performance of lithium batteries. In this context, they note that lithium-sulfur batteries are a very solid alternative to lithium-ion batteries. Stabilization problems related to its capacity can be resolved by using amylopectin, a polysaccharide (mainly good old corn starch).

Enveloping the battery’s lithium sulfur cathodes, with an encasing resembling the shell of an egg yolk (sulfur coated with an inexpensive polymer) also apparently improves the battery’s durability and performance.

Cornell has initiated a startup company to take the new and improved starch, egg-yolk shell battery to market. Maybe sometime soon, moderate and middle-income owners of electric cars that are less expensive than what is now available will be able to reduce their fear of driving long distances and feel confident about the life and efficiency of the batteries in their vehicles.

I avoided chemistry, physics and engineering in college. I knew I was not destined to become neither city planner nor designer at MIT when my first student-planned bridge went under water instead of over it. While my efforts were applauded by the Malthusians among my colleagues, they were not regarded highly by professors. Since graduation, unless supported by respected colleagues with a background in relevant sciences and engineering, I have been hesitant to suggest approval of science-driven energy innovations. I am a policy and program person. However, after review and discussions with trusted experts, I believe the Stanford and Cornell initiatives have a good chance to see the light of day, or, more appropriate, see the light in the market place. If one or both do, we will all be better off and the number of feasible alternative transportation fuels available to the consumer will grow. Hooray for copper, starch and eggs.

Arctic Leaf

The Battle Over Ethanol Takes Shape

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The decision isn’t scheduled until June but already opposing sides are converging on Washington, trying to pressure the Environmental Protection Agency over the 2014 Renewable Fuel Standard for ethanol.

Last week almost 100 members of the American Coalition for Ethanol descended on the nation’s capital for its annual “Biofuels Beltway March,” buttonholing 170 lawmakers and staffers from 45 states.  The object was to send a message to EPA Administrators Gina McCarthy to up the ante on how many billions of gallons the oil refining industry will be required to purchase this year.

The ethanol program is currently in turmoil.  The latest problem is rail bottlenecks that have slowed shipments and created supply shortages over the winter months.  Record-breaking cold and four-foot snow pack have been partly responsible but the rail lines are also becoming overcrowded.  With all that oil gushing down from the Bakken and Canadian crude now finding its way into tank cars as the Obama Administration postpones its decision over the Keystone Pipeline, ethanol is getting tangled in traffic.  .

“Ethanol for April delivery sold for about $3.02 a gallon on the Chico Board of Trade, an 81 percent increase over the low price during the past 12 months of $1.67 a gallon reached in November,” reported the Omaha World-Herald last Friday  “This weeks settlement price of $2.98 a gallon was the highest since July 2011.”  With only so much storage capacity, some ethanol refineries have been forced to shut down until the next train arrives to carry off the inventory.  As ethanol becomes mainstream, it is becoming more and more subject to market events beyond its control.

But the big decision will be EPA’s ruling in June.  In accord with the 2008 Renewable Fuel Act, Administrator McCarthy must set a “floor” for amount of ethanol refiners will have to incorporate into their blends during 2014.  The program ran into trouble last year when the 13.8 billion gallon requirement pushed ethanol beyond the 10 percent “blend wall” where the auto companies will not honor warrantees in older cars.  Refiners were forced to purchase compensating Renewable Identification Numbers (RINs), which exploded in value from pennies to $1.30 per gallon, forcing up the price of gasoline.  Contrary to expectations, gasoline consumption has actually declined over the last six years, from 142 billion gallons in 2008 to 134 billion in 2013 as a result of mileage improvements plus the lingering effects of the recession.  Last November McCarthy proposed reducing the 2014 from 14.4 billion gallons to 13 billion.  The industry has been crying “foul” ever since.

But there are other ways to fight back.  Last week in Crookson, gas stations were offering Minnesota drivers 85 cents off a gallon for filling up with E-85, the blend of 85 percent ethanol that many see as the real solution to the blend-wall problem.  “We want the public to understand there are different ratios of gasoline and ethanol and how they can save you money,” Greg LeBlac, of the Polk County Corn Growers, told the Fargo Valley News. 

At the annual meeting of the American Fuel and Petroleum Manufacturers (APFM) in Orlando last week, Anna Temple, product manager at WoodMac, made the case that the industry should forego efforts to raise the blend wall from 10 to 15 percent and instead shoot for the moon, leapfrogging all the way to E-85, where ethanol essentially replaces gasoline completely.  (The 15 percent only ensures starts in cold weather.)

“E-15 is a non-starter in terms of market share,” Temple told her audience, as reported by John Kingston’s in Platts.  http://blogs.platts.com/2014/03/25/eight-fillups/  She argued the incremental battle would absorb vast amounts of political capital yet still not be enough to absorb the 15-billion-gallon target for 2021.  Instead, Temple pointed to the growing fleet of flex-fuel vehicles that now numbers around 15 million, headed for 25 million in 2021 or 10 percent of the nation’s 250-million-car fleet.

“If U.S. drivers poured about 200,000 barrels-per-day of E-85 into their flex fuel cars in 2021, that would take care of about 17 percent of the scheduled ethanol mandate,” Temple said.  “It would only require that flex-fuel owners fill a 15-gallon tank eight times a year.”   The remainder would be absorbed in the 10 percent blend and ethanol producers would not have to cut output.

Platts’ Kingston checked the math and found that even this goal would leave ethanol consumption slightly above the blend wall at 10.5 percent.  “Still, the very modest number of eight fill-ups per flex fuel vehicles per year makes the whole blend wall issue seems a lot less daunting,” he confessed.

Of the 15 million people who own flex-fuel vehicles, of course, many don’t even realize it.  (The yellow gas cap or a rear-end decal are the giveaway.)  But the number of gas stations offering E-85 pumps is rising.  The Energy Information Administration now estimates the number at 2,500 with most of the growth taking place outside the Midwestern homeland.  California and New York each have more than 80 stations apiece.

The problem of rail bottlenecks can probably be solved by increasing the number of E-85 outlets and flex-fuel vehicles to bring supplies closer to the place of consumption.  Still, the industry would probably be happy to have a bigger renewable fuel mandate as well.

Arctic Leaf

No Sex-Just Smirking; No Lies-Just No Strategic Thinking; No Videotapes- Just Lots Of words And Ideology

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According to several well-known writers of blogs and columns, based on a recent study by North Carolina State University, EDV’s (electric cars, hybrids and plug ins) are not all they are cracked up to be. Because they may be powered by a coal or natural gas utilities, they spew pollutants, because hybrids may use gasoline, they emit ghg and other pollutants, because their production processes are “dirty,” they generate more pollutants than gasoline.

Electric cars in China have an overall impact on pollution that could be more harmful to health than gasoline vehicles…  EDVs ghg reduction will not make a big difference because the total number of vehicles in the U.S. only produces about 20 percent of all carbon emissions.”

I have seen higher numbers than stated by the writers concerning carbon emissions by cars and trucks fueled by gasoline. It is not clear whether the North Carolina study compared general supply chains to supply chain specifics. For example, EV engines use a proportionately large share of aluminum. Its mining probably emits more ghg than materials used in non evs. Yet, its use in cars, given its lighter weight, produces less emissions.

More relevant, perhaps, while recently there has been some retreat because of rising natural gas costs compared to coal costs, in the long term future, (perhaps aided by government regulations of carbon emissions,) conversion of coal based power generation to natural gas will  again trend upward and lower the total ghg allocated to EDVs.

The bloggers and columnists as well as the North Carolina scholars seem to believe in the theory that if you build it they will come.  Indeed, the most frequent comments on the models used in the study relate to one model, that is, a 42 percent EDV market share by 2050. It presumes a government cap on emissions.   Apparently, according to this model, any ghg reductions caused by EDVs will soon be filled up by other emitters. According to the study’s author, Joseph DeCarolis, ( interviewed by Will Oremus, a critic of the paper in his article in Future Tense, Jan. 27),   “It’s that there all this other stuff going on in this larger energy system that effects overall emissions.” I would add based on the study, DeCarolis presumes ghg emissions are fungible and equilibrium will result in 2050.

Diminishing the ghg importance of  EDVs ,  more than three decades out,  shifts  issues and initiates arguments over whether or not government should have a tougher cap; whether or not other sectors of the economy will illustrate more or less ghg emissions; whether or not technological advancements focused on ghg reduction across the economy will remain almost static; whether or not businesses will accept ghg reduction as a must or as part of  “conscientious capitalism” both to sustain profits and quality of life.

The continued development and increased sales of edvs are important to the nation’s long term effort to reduce ghg and other pollutants. But, until evs among edvs increase mileage per charge to remove owner fear of stalling out in either remote or congested places like freeways and until the price comes down and size increases for families with children, they will at best constitute a relatively small share of the new market for cars in the  near future. Even if the total numbers of edvs significantly increase their proportion of new car sales, many years will pass before they, will collectively, play a major role in lessening the nation’s carbon footprint.

Perfectibility not perfection should be a legitimate goal for all of us concerned with the environment. Individuals and groups concerned with the economic and social health of the nation should drop their ideological bundling boards. (Some of us are old enough to remember the real origins of the bundling board. Because of a shortage of space in many homes, it was used to separate males and females who often slept together before they were married in revolutionary days. I am not sure it was abandoned because mores changed, houses got bigger or people got splinters. I have no videotapes!)

2014 should witness the development of a non-partisan,non- ideological coalition of environmental, business, non-profit, academic  and government leaders to embrace  the need for an effective transitional alternative fuel strategy for new and existing cars and EDVs.  The embrace should respond to national and local objectives concerning the environment, the economy, and security and consumer well-being.   A good place to start would be to extend the use of natural gas based fuels, including ethanol and methanol.

Simultaneously, the coalition should encourage Detroit to expand production of flex fuel cars and the nation to implement a large scale flex fuel conversion program for existing cars.  Added to the coalition’s agenda should be development of a more open fuels market and support for intense research and development of EDV’s, particularly EVs.  Hopefully, evs will soon be   ready for prime time in the marketplace. Succinctly, we need both alternative fuels and evs.

Arctic Leaf

Can Ethylene Replace Gasoline?

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The effort to replace oil-based gasoline in our cars with similar fuels derived from natural gas took a big step forward last week with the announcement that Siluria, a promising start-up, will build a $15-million demonstration plant in Texas

The plant will produce ethylene, the most commonly produced industrial chemical in the world and the feedstock for a whole raft of products in the chemicals and plastics industry. But Siluria, which is not yet a public company, is also planning demonstration plants that will produce gasoline. Initial estimates are that the product could sell at half the price of gasoline derived from oil. If these projections prove to be anywhere close to reality, we could be on a path to a fuel economy that is finally able to cut its dependence on oil.

The idea of producing ethylene from natural gas has been around since the 1980s but achieved little success. Several major oil companies invested millions of dollars in the process but finally gave up on it. Jay Labinger, a Caltech chemist who did much of the initial research, finally wrote a paper in the 1980s warning other researchers that it was a waste of time. He may have given up too soon.

Siluria is a California-based startup that has received much of its funding from Silicon Valley investors who tried to move from computers and the Internet into the energy space over the last decade. So far their success hasn’t been great. In fact Vinod Khosla and other Silicon Valley energy entrepreneurs were the subject of an embarrassing critique on “60 Minutes” only two weeks ago. The Siluria venture, however, may be the gusher that makes up for all the other dry holes.

The 1980s efforts concentrated on heat-activated processes whereby methane is split into carbon and hydrogen and then recombined into the more complex ethylene, which has two double-bonded carbons and four hydrogens. All these efforts proved far too energy-intensive, however, and never became economical.

Siluria has been trying a different approach, seeking catalysts that would facilitate the process at much lower energy levels. Moreover, the company has spurned the more recent approach of trying to design molecules that fit the chemicals just right and gone back to the old shotgun approach where thousands of candidates are tried on a catch-as-catch-can basis.

Defying all expectations, the process seems to have worked. Siluria has come up with a catalyst that it says promotes the breakdown and subsequent reassembly of methane at very low energy levels. It has built pilot plants in San Francisco, Menlo Park and Hayward, California and last week announced plans for building a full-scale demonstration plant in La Porte, Texas in conjunction with Braskem, the largest petrochemical manufacturer in South America. If that isn’t proof that Siluria is on to something, what is

The implications of this development are enormous. Natural gas is two to six times more abundant than oil in the world and is now selling at 1/5th the price for an equivalent amount of energy. The traditional tandem pricing of oil and natural gas prices has now been broken and gas is functioning as a completely different commodity, much cheaper.

The difficulty all along has been that natural gas is hard to put into your gas tank. So far efforts have involved compressing natural gas, which means storing it at 3600 pounds per square inch, or liquefying it, which requires temperatures to be lowered to – 260 degrees F. Neither is very practical and would require a whole new auto engine and delivery infrastructure.

Efforts to convert gas into a liquid have concentrated around methanol, which is the simplest alcohol and has been used to power the Indianapolis 500 racing cars since the 1960s. But methanol is the deadly “wood alcohol” of the Prohibition Era and raises fears about poisoning – although gasoline is poisonous, too. The Environmental Protection Agency has never certified methanol for use in auto engines, although an M85 standard has been permitted in California.

Synthesizing gasoline through Siluria’s ethylene-based pathway could solve all these problems. Ed Dineen, CEO of Siluria, says that the gasoline product could sell at half the price of today’s gasoline. With more natural gas being found all the time – and with $1 billion being flared off uselessly around the world each year – any success in turning natural gas into a readily accessible automobile fuel could have a revolutionary impact on our entire economy.

Arctic Leaf

Ford Leads the Way

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The Ford Motor Company stepped front-and-center in the effort to fine alternatives to high-priced imported oil last week with the announcement that it will offer compressed natural gas (CNG) tank as an option in the F-150 pickup truck, its most popular brand that currently sells 700,000 models a year.

Now it won’t come cheap. There’s a $250-$350 charge for the vehicle to come “prepped” from the factory. That means putting hardened valves, valve seats, piston and rings into the V6 engine. But after that, there’s a $7-9000 charge for installing the CNG tank in the cargo bay – made considerably more expensive than in Europe because safety standards are interpreted in a way that makes them much more expensive. This lifts the showroom price from $24,000 to around $32,000. That’s a big chunk but Ford swears you’ll make it back in three years by substituting fuels.

With the price of gas at around $3.80 per gallon and the oil-equivalent of natural gas at around $1.20, those savings should add up fast.  Of course all this assumes that the price differential won’t narrow to its traditional level, but that doesn’t seem very likely now. Electrical plants have shown a tendency to move quickly back to cheaper coal if the price of gas rises, but the difference between the crack spread and the spark spread seems to have separated permanently, much to natural gas’s advantage.

All this is good news for those looking to substitute some of our abundant natural gas for foreign oil in our transport sector.  In fact, there’s a lot of progress being made right now:

Clean Energy Fuels of Newport Beach, CA already has a network of 360 natural gas fueling stations at truck stops along Interstate highways and is trying to build a complete national infrastructure.  NGV stations cost $750,000 a pop but Clean Energy is looking at the long term.  The ready availability of filling stations will help spur the conversion of giant 18-wheel diesel haulers, which most people see as the ripest target for conversion.

Heavy-duty fleet vehicles are making rapid progress.  Buses and garbage trucks are in the forefront. Eight out of ten new vehicles bought in 2012 by Waste Management, the leader in the field, were powered by natural gas.

There are now 120,000 gas vehicles on the road in the United States, according to Natural Gas Vehicles of America, the trade group.  Unfortunately, this constitutes only a tiny fraction of the 15.2 million NGVs worldwide. Iran, Pakistan and Argentina, improbably, are the leaders. We’re behind in making the transition, but there’s plenty of room to catch up.

In a report issued in June, Citi Research estimated that one-quarter of the world’s present consumption of oil could be replaced by natural gas under present conditions. More than 9 million barrels per day could be replaced in truck transport, 2 million of these in the US. Another 3 million b/d could be opted out in marine transport and 200,000 b/d in railroad locomotives.

All this would be fairly easy to transact since it involves large commercial organizations with centralized decision-making.  Sooner or later, however, this approach is likely to run up against limits.  The stumbling block will be the vastly more decentralized system of private automobiles, which still consumes 60 percent of our oil and involves a car in every garage and a gas station on every other corner. Here the problem of building an infrastructure and achieving widespread distribution is much more difficult.

The problem comes because reformers are viewing natural gas as a fuel instead of a feedstock. Compressed natural gas (CNG) and liquefied natural gas (LNG) are the most readily available options – and both are legal – but in the end they are going to have their limits. It will make much more sense to use methane as a feedstock for the manufacture of liquids, methanol in particular.  These will be much easier to transport and will substitute for gasoline in current car engines with only minimum adjustment – nothing like the $8000 required for the F-150. Valero has just opted to build a $700 million methanol manufacturing plant in St. Charles, Louisiana in anticipation of this demand. All depends on whether the Environmental Protection Agency decides to give a go-ahead to use methanol in car engines. The matter is pending.

So the effort to use our abundant natural gas resources to reduce our dependence on expensive, unpredictable and unreliable foreign sources of oil is making headway. Ford’s decision to equip the F-150 with CNG is a beginning. But there’s more to come.